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Transcendental dialectic is the science of antinomies, that is, of examining vain attempts of reason to escape from the enclosing circle of sensation and appearance into the unknowable world of things "in themselves."

Definition.com

Transcendental dialectic is the science dealing with antinomies which sets out to show that substance and cause and necessity are finite categories, modes of arrangement and classification which the mind applies to sense-experience, and reliably valid only for the phenomena that appear to such experience.

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